Diyne coordination chemistry: Reactions of [RuClH(CO)(PPh3)3] with diphenylbutadiyne and bis(phenylethynyl)mercury

Hill, Anthony F.; Melling, Richard P.

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Diyne coordination chemistry: Reactions of [RuClH(CO)(PPh3)3] with diphenylbutadiyne and bis(phenylethynyl)mercury

Date

1990-10-09

Authors

Hill, Anthony F.

Melling, Richard P.

Abstract

The reaction of the hydridometal complex [RuClH(CO)(PPh3)3] with 1,4-diphenyl-butadi-1,3-yne has been investigated and found to proceed with monoinsertion to give a coordinatively unsaturated σ-vinyl complex [Ru-{C(CCPh)CHPh} Cl(CO)(PPh3)2], which is also the major product of the reaction of [RuClH(CO) (PPh3)3] with [Hg(CCPh)2].

URI

https://hdl.handle.net/1885/733798088

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ANU Research Publications

Source

Journal of Organometallic Chemistry

Type

Journal article

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Publication

DOI

10.1016/0022-328X(90)85205-D

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Diyne coordination chemistry: Reactions of [RuClH(CO)(PPh<sub>3</sub>)<sub>3</sub>] with diphenylbutadiyne and bis(phenylethynyl)mercury

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