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Formation of ethane from mono-methyl palladium(II) complexes

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Date

2014-06-11

Authors

Lotz, Monica D.
Remy, Matthew S.
Lao, David B.
Ariafard, Alireza
Yates, Brian F.
Canty, Allan J.
Mayer, James M.
Sanford, Melanie S.

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Abstract

This article describes the high-yielding and selective oxidatively induced formation of ethane from mono-methyl palladium complexes. Mechanistic details of this reaction have been explored via both experiment and computation. On the basis of these studies, a mechanism involving methyl group transmetalation between PdII and PdIV interediates is proposed.

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http://www.scopus.com/inward/record.url?scp=84902281218&partnerID=8YFLogxK
 https://hdl.handle.net/1885/733758720

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ANU Research Publications

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Journal of the American Chemical Society

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Journal article

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10.1021/ja412338k

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