Novel syntheses of heterodinuclear phosphaalkenyl complexes: X-ray structure of [Ru{P(AuPPh<sub>3</sub>)=CHBu<sup>t</sup>}Cl<sub>2</sub>(CO)(PPh <sub>3</sub>)<sub>2</sub>]
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Bedford, Robin B.
Hill, Anthony F.
Jones, Cameron
White, Andrew J.P.
Williams, David J.
Wilton-Ely, James D.E.T.
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The reaction of [Ru(P=CHBut)Cl(CE)(PPh3)2] (E = O, S) with [AuX(PPh3)] (X = Cl, C≡CC6H4Me-4), HgCl2 or Hg2Cl2 leads via addition of the Au-X or Hg-Cl bonds across the Ru-P linkage to the heterodinuclear phosphaalkene complexes [Ru{P(AuPPh3)=CHBut}ClX(CE)(PPh3)2] and [Ru{P(HgCl)=CHBut}Cl2(CE)(PPh3)2].
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Chemical Communications
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