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ATRP-mediated continuous assembly of polymers for the preparation of nanoscale films

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Mertz, Damien
Ochs, Christopher J.
Zhu, Zhiyuan
Lee, Lillian
Guntari, Stefanie N.
Such, Georgina K.
Goh, Tor Kit
Connal, Luke A.
Blencowe, Anton
Qiao, Greg G.

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The continuous assembly of polymers (CAP) via atom transfer radical polymerisation (ATRP) is reported as an efficient approach for the preparation of dense, cross-linked, nanoscale engineered films as surface coatings, hollow capsules and replica particles. These films can be reinitiated to allow the preparation of thicker films without loss of film growth efficiency while maintaining similar film density.

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Chemical Communications

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