Hexahydroxytriphenylene for the synthesis of group 13 MOFs-a new inorganic building unit in a β-cristobalite type structure
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Leubner, S.
Bengtsson, V. E.G.
Inge, A. K.
Wahiduzzaman, M.
Steinke, F.
Jaworski, A.
Xu, H.
Halis, S.
Rönfeldt, P.
Reinsch, H.
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Two new, microporous MOFs of framework composition ((CH3)2NH2)2[M3O(HHTP)(HHTP)], M = Al3+, Ga3+, H6HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene, are described. Electron diffraction combined with molecular simulations show that these compounds crystallize in the β-cristobalite structure, containing a new type of trinuclear inorganic building unit for MOFs and radical anions.
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Dalton Transactions
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