Influence of pressure on a dysprosocenium single-molecule magnet

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dc.contributor.authorParmar, Vijay S.en
dc.contributor.authorThiel, Andreas M.en
dc.contributor.authorNabi, Rizwanen
dc.contributor.authorGransbury, Gemma K.en
dc.contributor.authorNorre, Marie S.en
dc.contributor.authorEvans, Peteren
dc.contributor.authorCorner, Sophie C.en
dc.contributor.authorSkelton, Jonathan M.en
dc.contributor.authorChilton, Nicholas F.en
dc.contributor.authorMills, David P.en
dc.contributor.authorOvergaard, Jacoben
dc.date.accessioned2025-05-30T05:30:30Z
dc.date.available2025-05-30T05:30:30Z
dc.date.issued2023-02-01en
dc.description.abstractThe effects of external pressure on a high-performing dysprosocenium single-molecule magnet are investigated using a combination of X-ray diffraction, magnetometry and theoretical calculations. The effective energy barrier (Ueff) decreases from ca. 1300 cm−1 at ambient pressure to ca. 1125 cm−1 at 3 GPa. Our results indicate that compression textless 1.2 GPa has a negligible effect on the Orbach process, but magnetic relaxation textgreater 1 GPa increases via Raman relaxation and/or quantum tunnelling of magnetisation.en
dc.description.statusPeer-revieweden
dc.format.extent4en
dc.identifier.issn1359-7345en
dc.identifier.otherBibtex:parmar_influence_2023en
dc.identifier.scopus85148671893en
dc.identifier.urihttps://hdl.handle.net/1885/733754670
dc.language.isoenen
dc.rightsPublisher: The Royal Society of Chemistryen
dc.sourceChemical Communicationsen
dc.titleInfluence of pressure on a dysprosocenium single-molecule magneten
dc.typeJournal articleen
dspace.entity.typePublicationen
local.bibliographicCitation.startpage2656–2659en
local.contributor.affiliationParmar, Vijay S.; Aarhus Universityen
local.contributor.affiliationThiel, Andreas M.; Aarhus Universityen
local.contributor.affiliationNabi, Rizwan; University of Manchesteren
local.contributor.affiliationGransbury, Gemma K.; University of Manchesteren
local.contributor.affiliationNorre, Marie S.; Aarhus Universityen
local.contributor.affiliationEvans, Peter; University of Manchesteren
local.contributor.affiliationCorner, Sophie C.; University of Manchesteren
local.contributor.affiliationSkelton, Jonathan M.; University of Manchesteren
local.contributor.affiliationChilton, Nicholas F.; University of Manchesteren
local.contributor.affiliationMills, David P.; University of Manchesteren
local.contributor.affiliationOvergaard, Jacob; Aarhus Universityen
local.identifier.citationvolume59en
local.identifier.doi10.1039/D2CC06722Fen
local.identifier.purecedf947c-5742-4418-9391-f4ec66051c0fen
local.identifier.urlhttps://www.scopus.com/pages/publications/85148671893en
local.type.statusPublisheden

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