Diisopropylaminomethylidyne complexes of iron, chromium, molybdenum and tungsten

Anderson, Stephen; Hill, Anthony F.

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Diisopropylaminomethylidyne complexes of iron, chromium, molybdenum and tungsten

Date

1990-08-11

Authors

Anderson, Stephen

Hill, Anthony F.

Abstract

Treatment of [M(CO)n] (n = 6, M = Cr, Mo, W; n = 5, M = Fe) successively with LiNiPr2, (CF3CO)2O, and PPh3 leads to the thermally stable diisopropylaminomethylidyne complexes [M(CNiPr2)(O2CCF3)(CO)3(PPh3)] (M = Cr, Mo, W) and [Fe(CNiPr2)(O2CCF3)(CO)2(PPh3)] in high yield. The latter is the first neutral mononuclear carbyne complex of iron.

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https://hdl.handle.net/1885/733798093

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ANU Research Publications

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Journal of Organometallic Chemistry

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Journal article

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Publication

DOI

10.1016/0022-328X(90)87274-H

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Diisopropylaminomethylidyne complexes of iron, chromium, molybdenum and tungsten

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