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Heterocyclic arsinocarbynes <i>via</i> tandem transmetallation

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Date

2021

Authors

Frogley, Benjamin J.
Hill, Anthony F.
Kirk, Ryan M.

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Research Projects

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Abstract

Gold(i)-catalysed tandem transmetallation (Sn -> Au -> As) of the stannylcarbyne [W(equivalent to(CSnBu3)-Bu-n)(CO)(2)(Tp*)] (Tp* = hydrotris-(dimethylpyrazolyl)borate) with haloarsines gives direct access to a range of novel arsinocarbyne complexes, LnM equivalent to CAsR2, including unusual heterocyclic phenarsazininyl and arsolyl examples.

Description

Keywords

Tp-asterisk, Complexes, Carbyne, Mo, Coordination, Aromaticity, Arsaalkenes, Carbido, Carbon, Bi

Citation

URI

https://hdl.handle.net/1885/733809893

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ANU Research Publications

Source

Chemical Communications

Type

Review

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Publication

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DOI

10.1039/d1cc03015a

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