Synthesis of Organometallic Hydrotris-(pyrazol-1-yl)boratoruthenium(ii) Complexes
| dc.contributor.author | Hill, Anthony F | en |
| dc.date.accessioned | 2026-01-02T08:41:39Z | |
| dc.date.available | 2026-01-02T08:41:39Z | |
| dc.date.issued | 1990-09-25 | en |
| dc.description.abstract | The reactions of K[HB(pz)3] (pz = pyrazol-1-yl) with the coordinatively unsaturated σ-vinyl complexes [Ru(CR=CHR)Cl(CO)(PPh3)2] (R = H, Me, C6H5) proceed with loss of a chloride and a phosphine ligand to provide the compounds [Ru(CR=CHR)(CO)(PPh3){HB(pz)3}] in high yield. Similar treatment of the complex [Ru(C6H4Me-4)Cl(CO)(PPh3)2] leads to the related σ-aryl derivative [Ru(C6H4Me-4)(CO)(PPh3){HB(pz)3}] whilst the complex [RuClH(CO)(PPh3)3] treated successively with diphenylbutadiyne and K[HB(pz)3] provides the unusual derivative [Ru{C(C=CPh) CHPh}(CO)(PPh3){HB(pz)3}]. | en |
| dc.description.status | Peer-reviewed | en |
| dc.format.extent | 4 | en |
| dc.identifier.issn | 0022-328X | en |
| dc.identifier.other | WOS:A1990EA97400013 | en |
| dc.identifier.other | ORCID:/0000-0003-2167-0604/work/181799543 | en |
| dc.identifier.scopus | 0002946244 | en |
| dc.identifier.uri | https://hdl.handle.net/1885/733802149 | |
| dc.language.iso | en | en |
| dc.source | Journal of Organometallic Chemistry | en |
| dc.title | Synthesis of Organometallic Hydrotris-(pyrazol-1-yl)boratoruthenium(ii) Complexes | en |
| dc.type | Journal article | en |
| dspace.entity.type | Publication | en |
| local.bibliographicCitation.lastpage | C38 | en |
| local.bibliographicCitation.startpage | C35 | en |
| local.contributor.affiliation | Hill, Anthony F; University of Warwick | en |
| local.identifier.citationvolume | 395 | en |
| local.identifier.doi | 10.1016/0022-328X(90)85285-7 | en |
| local.identifier.pure | c60a18b9-892e-45d5-a254-9f565516a857 | en |
| local.identifier.url | https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=anu_research_portal_plus2&SrcAuth=WosAPI&KeyUT=WOS:A1990EA97400013&DestLinkType=FullRecord&DestApp=WOS_CPL | en |
| local.identifier.url | https://www.scopus.com/pages/publications/0002946244 | en |
| local.type.status | Published | en |