Photoaffinity-labeled peptoids and depsipeptides by multicomponent reactions
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Henze, Michael
Kreye, Oliver
Brauch, Sebastian
Nitsche, Christoph
Naumann, Kai
Wessjohann, Ludger A.
Westermann, Bernhard
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Abstract
Photoaffinity tags can be incorporated easily into peptoids and congeners by the Ugi and Passerini multicomponent reactions. Products related to photo-methionine and photo-leucine can be accomplished by diazirine-containing building blocks. The same protocols can be used to synthesize derivatives with benzophenone photo cross-linkers.
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Synthesis
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