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An Organometallic Erbium Bismuth Cluster Complex Comprising a Bi $_6$ $^6–$ Zintl Ion

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2024

Authors

Benner, Florian
Pugliese, Elizabeth R.
Marsden, Reece Q.
Staples, Richard J.
Chilton, Nicholas F.
Demir, Selvan

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Abstract

An organometallic erbium bismuth cluster complex,[K(THF)4]2[Cp*2Er2Bi6] (1), featuring a heterometallocubanecore was isolated. The cube emerges from the rare Bi66− Zintl ion,bridging two erbium centers for the first time. SQUID magneto-metry and ab initio calculations uncovered dominant antiferro-magnetic coupling enabled through the chair-like hexabismuthanion. The gained insight will promote the design of futurepolynuclear magnetic molecules comprising prolate lanthanideions

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https://hdl.handle.net/1885/733755834

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ANU Research Publications

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Inorganic Chemistry

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Journal article

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DOI

10.1021/acs.inorgchem.4c02636

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