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Catalytic role of amines in activation of PhICl<sub>2</sub>from a computational point of view

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2021-09-16

Authors

Farshadfar, Kaveh
Ariafard, Alireza

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Abstract

We thoroughly investigated mechanistic features of dichlorination of diazoacetates using PhICl2catalysed by pyridine. We found that the pyridine serves as a catalyst for decomposition of PhICl2to PhI and Cl2, leading to the dichlorination step being driven by thein situgenerated Cl2.

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https://hdl.handle.net/1885/733800691

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ANU Research Publications

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Chemical Communications

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Journal article

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10.1039/d1cc03618a

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