Two Counterintuitive Routes to an Iron Alkylidyne Complex
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Anderson, Stephen
Hill, Anthony F.
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The cationic aminomethylidyne complex [Fe- (≡CNiPr2)(CO)3(PPh3)]+ has been prepared by two unexpected routes: (i) Iodination of the carbamoyl complex [Fe(η2-OCNiPr2)(CF3)(CO)2(PPh3)] and (ii) O-trifluoroacetylation of the carbamoylate [Fe{C(=O)NiPr2}(CO4]-Li, a reaction which shows an unusual solvent dependence.
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Organometallics
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