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Two Counterintuitive Routes to an Iron Alkylidyne Complex

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Date

1995

Authors

Anderson, Stephen
Hill, Anthony F.

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Research Projects

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Abstract

The cationic aminomethylidyne complex [Fe- (≡CNiPr2)(CO)3(PPh3)]+ has been prepared by two unexpected routes: (i) Iodination of the carbamoyl complex [Fe(η2-OCNiPr2)(CF3)(CO)2(PPh3)] and (ii) O-trifluoroacetylation of the carbamoylate [Fe{C(=O)NiPr2}(CO4]-Li, a reaction which shows an unusual solvent dependence.

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https://hdl.handle.net/1885/733798089

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ANU Research Publications

Source

Organometallics

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Journal article

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Publication

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DOI

10.1021/om00004a007

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