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The coupling of methylene and vinyl ligands at a ruthenium(II) centre

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Hill, Anthony F.
Ho, Chean T.
Wilton-Ely, James D.E.T.

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The reaction of [Ru(CH=CH2)Cl(CO)(PPh3)2] with diazomethane provides the allyl complex [Ru(η3-CH2CHCH2)Cl(CO)(PPh 3)2] which is also the product of the reactions of [RuHCl(CO)(PPh3)3] with either allene or propyne and which reacts subsequently with NaS2CNMe2 to provide [RuH(S2CNMe2)(CO)(PPh3)2] and allene.

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Chemical Communications

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