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Aryl-Fluoride Bond-Forming Reductive Elimination from Nickel(IV) Centers

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Date

2019-08-21

Authors

Meucci, Elizabeth A.
Ariafard, Alireza
Canty, Allan J.
Kampf, Jeff W.
Sanford, Melanie S.

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Abstract

The treatment of pyridine- and pyrazole-ligated NiII σ-aryl complexes with Selectfluor results in C(sp2)-F bond formation under mild conditions. With appropriate design of supporting ligands, diamagnetic NiIV σ-aryl fluoride intermediates can be detected spectroscopically and/or isolated during these transformations. These studies demonstrate for the first time that NiIV σ-aryl fluoride complexes participate in challenging C(sp2)-F bond-forming reductive elimination to yield aryl fluoride products.

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https://hdl.handle.net/1885/733795592

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ANU Research Publications

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Journal of the American Chemical Society

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Journal article

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10.1021/jacs.9b06896

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