The beauty of low symmetry: Non-statistical assembly of [Pd<sub>2</sub>(L<sub>A</sub>)(L<sub>B</sub>)(L<sub>C</sub>)(L<sub>D</sub>)]<sup>4+</sup> cages
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Faulkner, Logan A.V.
Crowley, James D.
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Clever and co-workers have developed an elegant method for the quantitative synthesis of a low-symmetry heteroleptic [Pd2(LA)(LB)(LC)(LD)]4+ cage. The cage is formed under thermodynamic control and can be accessed through multiple different pathways. Compared with their high-symmetry siblings, these types of low-symmetry cages should display enhanced molecular-recognition properties (selectivity).
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Chem
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