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In-depth insights of inhibitory behaviour of 2-amino-4-methylthiazole towards galvanised steel in neutral NaCl solution

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dc.contributor.authorDeng, Qiushien
dc.contributor.authorJeschke, Steffenen
dc.contributor.authorMurdoch, Billy J.en
dc.contributor.authorHirth, Sabineen
dc.contributor.authorEiden, Philippen
dc.contributor.authorGorges, Jan N.en
dc.contributor.authorKeil, Patricken
dc.contributor.authorChen, Xiao Boen
dc.contributor.authorCole, Ivanen
dc.date.accessioned2026-06-11T08:40:44Z
dc.date.available2026-06-11T08:40:44Z
dc.date.issued2022-05-01en
dc.description.abstractInhibitory behaviour of 2-amino-4-methyl-thiazole (2AT-Me) towards electro-galvanised steel (ZE) was investigated in neutral NaCl solution by electrochemical and surface analyses. It revealed that 2AT-Me acts as a mixed-type inhibitor with pronounced inhibition efficiency above 90% at a concentration of 15 mM. The adsorption behaviour of 2AT-Me upon ZE surface aligns with the Temkin adsorption isotherm. Moreover, surface studies illustrated that the formed protective film exhibits a multi-layered spatial structure comprising of passive oxides and inhibitor layers. The findings show promises for deploying small thiazole-based compounds in corrosion inhibition of ZE and zinc surfaces.en
dc.description.sponsorshipThe authors are grateful to the financial support of BASF Coatings GmbH, Germany through a research contract with RMIT University . The authors also acknowledge the facilities, and the scientific and technical assistance of the RMIT University's Microscopy & Microanalysis Facility, a linked laboratory of the Microscopy Australia. Q.D. is supported by BASF Coatings GmbH for the PhD scholarships.en
dc.description.statusPeer-revieweden
dc.identifier.issn0010-938Xen
dc.identifier.otherORCID:/0000-0001-6582-1457/work/217149510en
dc.identifier.scopus85125471578en
dc.identifier.urihttps://hdl.handle.net/1885/733810433
dc.language.isoenen
dc.rightsPublisher Copyright: © 2022 Elsevier Ltden
dc.sourceCorrosion Scienceen
dc.subjectA: Galvanised steelen
dc.subjectB: EIS, XPS depth profile, XPS, SEM-FIBen
dc.subjectC: Neutral corrosion inhibitoren
dc.titleIn-depth insights of inhibitory behaviour of 2-amino-4-methylthiazole towards galvanised steel in neutral NaCl solutionen
dc.typeJournal articleen
dspace.entity.typePublicationen
local.contributor.affiliationDeng, Qiushi; Royal Melbourne Institute of Technology Universityen
local.contributor.affiliationJeschke, Steffen; Royal Melbourne Institute of Technology Universityen
local.contributor.affiliationMurdoch, Billy J.; Royal Melbourne Institute of Technology Universityen
local.contributor.affiliationHirth, Sabine; BASFen
local.contributor.affiliationEiden, Philipp; BASFen
local.contributor.affiliationGorges, Jan N.; BASFen
local.contributor.affiliationKeil, Patrick; Royal Melbourne Institute of Technology Universityen
local.contributor.affiliationChen, Xiao Bo; Royal Melbourne Institute of Technology Universityen
local.contributor.affiliationCole, Ivan; Royal Melbourne Institute of Technology Universityen
local.identifier.citationvolume199en
local.identifier.doi10.1016/j.corsci.2022.110206en
local.identifier.pure41f06c52-be5a-4646-925b-ac0d7c5d6895en
local.identifier.urlhttps://www.scopus.com/pages/publications/85125471578en
local.type.statusPublisheden

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