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Reactions of transition metal σ-acetylides. VIII. Preparation and properties of some aryldiazo-vinylidene complexes

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Date

1987-02-24

Authors

Bruce, Michael I.
Humphrey, Mark G.
Liddell, Michael J.

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Abstract

Fourteen aryldiazovinylidene complexes of ruthenium and osmium have been made by addition of aryldiazonium cations to the appropriate σ-acetylides. Their properties and spectra (including FAB-MS) are described, and reactions with MeOH, hydride and methoxide are reported. Addition to and protonation, alkylation, and cyclomanganation of the aryldiazo functions are also described.

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https://hdl.handle.net/1885/733803910

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ANU Research Publications

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Journal of Organometallic Chemistry

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Journal article

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DOI

10.1016/0022-328X(87)80328-5

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