Reactions of transition metal σ-acetylides. VIII. Preparation and properties of some aryldiazo-vinylidene complexes
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Bruce, Michael I.
Humphrey, Mark G.
Liddell, Michael J.
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Fourteen aryldiazovinylidene complexes of ruthenium and osmium have been made by addition of aryldiazonium cations to the appropriate σ-acetylides. Their properties and spectra (including FAB-MS) are described, and reactions with MeOH, hydride and methoxide are reported. Addition to and protonation, alkylation, and cyclomanganation of the aryldiazo functions are also described.
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Journal of Organometallic Chemistry
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