A diazoalkane complex of titanium
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Kool, Lawrence B.
Rausch, Marvin D.
Alt, Helmut G.
Herberhold, Max
Hill, Anthony F.
Thewalt, Ulf
Wolf, Brigitte
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Abstract
(cp)2Ti(PMe3)2 (cp=η5- C5H5) and (cp)2Ti(CO)(PMe3) react with diphenyldiazomethane to yield (cp)2Ti(NNCPh2) (PMe3), the crystal structure of which has been determined, containing a monodentate diazoalkane ligand end-on co-ordinated through nitrogen.
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Journal of the Chemical Society, Chemical Communications
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