The synthesis of η<sup>2</sup>-thioketenyl complexes of molybdenum and tungsten

dc.contributor.author	Hill, Anthony F.	en
dc.contributor.author	Malget, John M.	en
dc.date.accessioned	2026-01-01T16:41:34Z
dc.date.available	2026-01-01T16:41:34Z
dc.date.issued	1996	en
dc.description.abstract	The complexes [M(η2-OCCR)(CO)L(Tp)] [M = Mo, W; L = P(OMe)3, PMe2Ph, PPh3; R = C6H4Me-4; Tp = hydrotris(pyrazol-1-yl)borate] are obtained from [M(≡CR)(CO)2(Tp)] and L under photolysis and these react with Lawesson's reagent (S2PC6H4OMe-4)2 to provide thioketenyl complexes [M(η2-SCCR)(CO)L(Tp)] one example of which (M = W, L = PMe2Ph) is also obtained from the reaction of [W(η2-ClCCR)Cl(CO)(Tp)] with NaSH in the presence of PMe2Ph.	en
dc.description.status	Peer-reviewed	en
dc.format.extent	2	en
dc.identifier.issn	1359-7345	en
dc.identifier.other	ORCID:/0000-0003-2167-0604/work/171153972	en
dc.identifier.scopus	0141461289	en
dc.identifier.uri	https://hdl.handle.net/1885/733801636
dc.language.iso	en	en
dc.source	Chemical Communications	en
dc.title	The synthesis of η<sup>2</sup>-thioketenyl complexes of molybdenum and tungsten	en
dc.type	Journal article	en
dspace.entity.type	Publication	en
local.bibliographicCitation.lastpage	1178	en
local.bibliographicCitation.startpage	1177	en
local.contributor.affiliation	Hill, Anthony F.; Department of Chemistry	en
local.contributor.affiliation	Malget, John M.; Imperial College London	en
local.identifier.doi	10.1039/CC9960001177	en
local.identifier.pure	e81e8159-aaad-428b-99ef-a23b5a77aa5e	en
local.identifier.url	https://www.scopus.com/pages/publications/0141461289	en
local.type.status	Published	en

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