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Hydrogenative depolymerization of silicon-modified polyureas

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Liu, Xin
Zuo, Yujing
Kallmeier, Fabian
Mejía, Esteban
Tin, Sergey
de Vries, Johannes G.
Baráth, Eszter

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Silicon-modified polyureas were depolymerized by hydrogenation in the presence of Ru and Mn catalysts. Yields of up to 84% of the aliphatic diamine and 81% of silicon-containing diamine were achieved with a commercially available PNP-Ru catalyst.

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Chemical Communications

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