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Alkynyltellurolato ligands including a solvatochromic rhenium(i) complex

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2025-03-17

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Burt, Liam K.
Kirk, Ryan M.
Hill, Anthony F.

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Alkynyltellurolato complexes LnM-Te-C = CR (LnM = CpFe(CO)2, CpFe(CO)(PPh3), Re(CO)3(bipy); R = Ph, SiMe3) arise via tellurium insertion into alkynyllithiums followed by metathesis with the corresponding metal halide complex. The rhenium(i) complex displays solvatochromism (hypsochromic shift in polar solvents) for the inter-ligand (TeC CR to bipy) charge transfer which is not, however, observed for the lighter analogue [Re(SeC CSiMe3)(CO)3(bipy)].

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http://www.scopus.com/inward/record.url?scp=105001802473&partnerID=8YFLogxK
 https://hdl.handle.net/1885/733753248

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Chemical Communications

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10.1039/d5cc00770d

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