Cultural advice

The Australian National University acknowledges, celebrates and pays our respects to the Ngunnawal and Ngambri people of the Canberra region and to all First Nations Australians on whose traditional lands we meet and work, and whose cultures are among the oldest continuing cultures in human history.

Aboriginal and Torres Strait Islander peoples are advised that ANU Library collections may include images, names, voices, and other representations of deceased persons.

Material in the collection may contain terms, language or views that reflect the period in which the item was created and may be considered inappropriate today.

Reactions of transition metal acetylide complexes. IV. Synthesis and X-ray structure of a bromovinylidene complex, [Ru{CCBr(C<sub>6</sub>H<sub>4</sub>Br-4)}(PPh<sub>3</sub>)<sub>2</sub>(η-C<sub>5</sub>H<sub>5</sub>)][Br<sub>3</sub>] · CHCl<sub>3</sub>

Simple item page
dc.contributor.authorBruce, Michael I.en
dc.contributor.authorHumphrey, Mark G.en
dc.contributor.authorKoutsantonis, George A.en
dc.contributor.authorNicholson, Brian K.en
dc.date.accessioned2026-01-07T09:41:41Z
dc.date.available2026-01-07T09:41:41Z
dc.date.issued1985-12-03en
dc.description.abstractHalogens react with ruthenium acetylide complexes to give dark green halovinylidene derivatives. In one case, bromination of the phenyl ring of the parent phenylacetylide complex occurs, as shown by the X-ray structure of [Ru{CCBr(C6H4Br-4)}(PPh3)2(η-C5H5)] [Br3] · CHCl3. The RuC and CC distances are 1.85(1) and 1.31(2) Å, respectively.en
dc.description.sponsorshipAcknowledgements. Financial support of this work from the Australian Research Grants Scheme is gratefully acknowledged. MGH is the holder of a Commonwealth Post-Graduate Research Award.en
dc.description.statusPeer-revieweden
dc.identifier.issn0022-328Xen
dc.identifier.otherORCID:/0000-0002-4433-6783/work/162949536en
dc.identifier.scopus4243458522en
dc.identifier.urihttps://hdl.handle.net/1885/733803906
dc.language.isoenen
dc.sourceJournal of Organometallic Chemistryen
dc.titleReactions of transition metal acetylide complexes. IV. Synthesis and X-ray structure of a bromovinylidene complex, [Ru{CCBr(C<sub>6</sub>H<sub>4</sub>Br-4)}(PPh<sub>3</sub>)<sub>2</sub>(η-C<sub>5</sub>H<sub>5</sub>)][Br<sub>3</sub>] · CHCl<sub>3</sub>en
dc.typeJournal articleen
dspace.entity.typePublicationen
local.bibliographicCitation.lastpagec50en
local.bibliographicCitation.startpagec47en
local.contributor.affiliationBruce, Michael I.; University of Adelaideen
local.contributor.affiliationHumphrey, Mark G.; Jordan Laboratoriesen
local.contributor.affiliationKoutsantonis, George A.; University of Adelaideen
local.contributor.affiliationNicholson, Brian K.; University of Waikatoen
local.identifier.citationvolume296en
local.identifier.doi10.1016/0022-328X(85)80383-1en
local.identifier.pure85f6be12-81f9-4515-a75b-ff86150cf45fen
local.identifier.urlhttps://www.scopus.com/pages/publications/4243458522en
local.type.statusPublisheden

Downloads

Collections

ANU Research Publications

DSpace software copyright © 2002-2026 LYRASIS