Mercuriophosphaalkene-P complexes: Crystal structure of [Ru{P(=CHBu<sup>t</sup>)HgC<sub>5</sub>H<sub>4</sub>Fe(η-C<sub>5</sub>H <sub>5</sub>)}Cl<sub>2</sub>(CO)(PPh<sub>3</sub>)<sub>2</sub>]

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Hill, Anthony F.
Jones, Cameron
White, Andrew J.P.
Williams, David J.
Wilton-Ely, James D.E.T.

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Stable complexes of mercuriophosphaalkenes have resulted from the addition of organomercury halides to the Ru-P bond of [Ru(P=CHBut)Cl(CA)(PPh3)2] (A = O or S), including the structurally characterised complex [Ru{P(=CHBut)HgC5H4-Fe(η-C 5H5)}Cl2(CO)(PPh3)2].

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Journal of the Chemical Society - Dalton Transactions

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