Bubbles, Thin Films and Ion Specificity
Abstract
Bubbles in water are stabilised against coalescence by the addition of salt. The white froth in seawater but not in freshwater is an example of salt-stabilised bubbles. A range of experiments have been carried out to investigate this simple phenomenon, which is not yet understood. ¶ The process of thin film drainage between two colliding bubbles relates to surface science fields including hydrodynamic flow, surface forces, and interfacial rheology. Bubble coalescence inhibition also stands alongside the better known Hofmeister series as an intriguing example of ion specificity: While some electrolytes inhibit coalescence at around 0.1M, others show no effect. The coalescence inhibition of any single electrolyte depends on the combination of cation and anion present, rather than on any single ion. ¶ ...