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Stereospecific effects of asymmetric ligands in cobalt (III) complexes

MacDermott, Thomas Edward


In the study of the effects of asymmetric groups in metal complexes, by far the most commonly used ligand has been propylenediamine. This base is a bidentate ligand and its metal complexes show a close chemical resemblance to those of ethylenediamine, so that any complex of ethylenediamine can be paralleled using propylenediamine. X-ray and infra-red studies show that the metal ligand ring in both ethylenediamine and propylenediamine complexes assumes a non-planar configuration. The...[Show more]

CollectionsOpen Access Theses
Date published: 1962
Type: Thesis (PhD)
DOI: 10.25911/5d6c3cd157fb7


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