Substitution at an octahedral metal centre
Date
1962
Authors
Bosnich, Brice Michael
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Abstract
This thesis contains most of the observations, experiments
and conclusions resulting from work on the substitution reactions
of some octahedral metal complexes. It is divided into four parts.
The first chapter is a summary of the effects which are expected
to control the rates of inorganic nucleophilic substitutions.
The results discussed are those which the author considers are peculiarly
inorganic rather than organic; although some overlap is inevitable.
It is not intended to be a literature review, and is restricted
mainly to octahedral systems. A discussion of the reactions
of square planar complexes is not given, nor is any discussion made
in regard to electron transfer reactions. The succeeding three chapters have their individual introductions.
The intended purpose of these introductions is to give a
brief survey of the previous work carried out on the particular problem
under investigation. It was hoped by this to indicate clearly
that a problem existed, and that it might be solved by the experiments
that have been carried out. It was considered that the nature of the
chosen topics did not warrant one long-, review type and perhaps perfunctory
general introduction at the beginning of the thesis.
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Keywords
Chemical reactions, Metals, Substitution reactions, Metal complexes
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Thesis (PhD)
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