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Thiol-thione equilibria in nitrogenous Heterocyclic Mercapto-compounds

Barlin, Gordon Bruce

Description

Two different tautomeric forms may be written for monoaza-heterocyclic mereapto-compounds, one with the mobile hydrogen atom on sulphur and the other with the mobile hydrogen on nitrogen. For example 4-mercaptopyridine may exist in the tautomeric forms: (l; R = K) or' (II; R = H).Additional NH forms are possible for polyazaheterocyclic mereapto-compounds. The tautomerism of the mercapto-derivatives of six-membered rings has been little examined. Isolated qualitative studies of the...[Show more]

CollectionsOpen Access Theses
Date published: 1959
Type: Thesis (PhD)
URI: http://hdl.handle.net/1885/95492

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