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Insertion reactions of unsymmetrical ester-activated alkynes with o -benzylamine palladacycles: A regioselectivity study.

Kelly, Amy; Macgregor, Stuart A; Willis, Anthony; Nelson, John H; Wenger, Eric

Description

The regioselectivities of the insertion reactions of RC≡CCO2Et (R=Ph, CF3) into the aryl-palladium bond of several five-membered, ortho-palladated dimethylbenzylamine complexes, [PdCl(C6H4CH2NMe2-κC,N)] 2 (1), [PdCl(C6H4CH2NMe2-κC,N)(L)] [L=PEt3 (2),

CollectionsANU Research Publications
Date published: 2003
Type: Journal article
URI: http://hdl.handle.net/1885/94246
Source: Inorganica Chimica Acta
DOI: 10.1016/S0020-1693(03)00149-X

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