Mononuclear and binuclear complexes of platinum(0) containing (alkynyl)phenylsilanes
Bennett, Martin; Cobley, Christopher; Hockless, David; Klettke, Thomas
Description
Reaction of bis(cycloocta-1,5-diene)platinum(0) with the (alkynyl)phenylsilanes Ph3SiC2But, Ph2Si(C2But)2 and PhSi(C2But)3 gives, respectively, [Pt(Ph3SiC2But)2] (1b), [Pt{Ph2Si(C2But)2}]2 (2b), and [Pt {PhSi(C2But)3}]2 (4b), which contain zerovalent platinum atoms coordinated by two alkyne units. Spectroscopic data indicate that (2b) and (4b) contain two PtC4 and two SiC4 tetrahedra joined at the corners. X-Ray crystallography shows that complex (4b) is isostructural and isomorphous with the...[Show more]
Collections | ANU Research Publications |
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Date published: | 1999 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/93753 |
Source: | Australian Journal of Chemistry |
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