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The first sideways-bonded peroxo complex for a tetraaminecobalt(III) species

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Rahman, A F M; Jackson, William Gregory; Willis, Anthony

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Cobalt(II) salts react with H2O2 in the presence of 2 equiv of tetramethylethylenediamine (tmen) to produce a stable sideways bonded mononuclear peroxo complex [Co(tmen)2O2]ClO4 which has been characterized chemically and by a single crystal X-ray determination. This is the first such tetraaminecobalt(III) complex, indeed, the first for any tetraaminemetal ion complex. The mononuclear peroxo complex can also be synthesized by O22- anation of cis-[Co(tmen) 2(OH2)2]3+. This reaction is reversed...[Show more]

dc.contributor.authorRahman, A F M
dc.contributor.authorJackson, William Gregory
dc.contributor.authorWillis, Anthony
dc.date.accessioned2015-12-13T23:09:24Z
dc.identifier.issn0020-1669
dc.identifier.urihttp://hdl.handle.net/1885/86985
dc.description.abstractCobalt(II) salts react with H2O2 in the presence of 2 equiv of tetramethylethylenediamine (tmen) to produce a stable sideways bonded mononuclear peroxo complex [Co(tmen)2O2]ClO4 which has been characterized chemically and by a single crystal X-ray determination. This is the first such tetraaminecobalt(III) complex, indeed, the first for any tetraaminemetal ion complex. The mononuclear peroxo complex can also be synthesized by O22- anation of cis-[Co(tmen) 2(OH2)2]3+. This reaction is reversed in acid, and this offers the potential to develop Co(III) catalyzed oxidation reactions.
dc.publisherAmerican Chemical Society
dc.sourceInorganic Chemistry
dc.titleThe first sideways-bonded peroxo complex for a tetraaminecobalt(III) species
dc.typeJournal article
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.citationvolume43
dc.date.issued2004
local.identifier.absfor030207 - Transition Metal Chemistry
local.identifier.ariespublicationMigratedxPub16064
local.type.statusPublished Version
local.contributor.affiliationRahman, A F M, University of New South Wales, ADFA
local.contributor.affiliationJackson, William Gregory, University of New South Wales, ADFA
local.contributor.affiliationWillis, Anthony, College of Physical and Mathematical Sciences, ANU
local.description.embargo2037-12-31
local.bibliographicCitation.issue24
local.bibliographicCitation.startpage7558
local.bibliographicCitation.lastpage7560
local.identifier.doi10.1021/ic040044z
dc.date.updated2015-12-12T08:19:05Z
local.identifier.scopusID2-s2.0-9444294995
CollectionsANU Research Publications

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