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Facile reduction of coordinated α-imino acids to amino acids by dithionite and borohydride.

Pearce, Dierdre; Hartshorn, Richard; Sargeson, Alan

Description

Sodium dithionite was found to reduce a range of α-iminoacidato ligands, chelated to cobalt(III), to the related α-aminoacidato species. For the bis(1,2-ethanediamine) system, the distribution of the products showed a small stereoselectivity towards the

dc.contributor.authorPearce, Dierdre
dc.contributor.authorHartshorn, Richard
dc.contributor.authorSargeson, Alan
dc.date.accessioned2015-12-13T22:23:01Z
dc.date.available2015-12-13T22:23:01Z
dc.identifier.issn1477-9226
dc.identifier.urihttp://hdl.handle.net/1885/72565
dc.description.abstractSodium dithionite was found to reduce a range of α-iminoacidato ligands, chelated to cobalt(III), to the related α-aminoacidato species. For the bis(1,2-ethanediamine) system, the distribution of the products showed a small stereoselectivity towards the
dc.publisherRoyal Society of Chemistry
dc.sourceDalton Transactions
dc.subjectKeywords: Chelation; Molecules; pH effects; Reduction; Imino acids; Amino acids
dc.titleFacile reduction of coordinated α-imino acids to amino acids by dithionite and borohydride.
dc.typeJournal article
local.description.notesImported from ARIES
local.description.refereedYes
dc.date.issued2002
local.identifier.absfor030503 - Organic Chemical Synthesis
local.identifier.ariespublicationMigratedxPub3309
local.type.statusPublished Version
local.contributor.affiliationPearce, Dierdre, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHartshorn, Richard, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationSargeson, Alan, College of Physical and Mathematical Sciences, ANU
local.bibliographicCitation.startpage1747
local.bibliographicCitation.lastpage1752
dc.date.updated2015-12-11T08:02:03Z
local.identifier.scopusID2-s2.0-0036009975
CollectionsANU Research Publications

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