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Use of spin traps to measure the addition and fragmentation rate coefficients of small molecule RAFT-adduct radicals

Chernikova, Elena; Golubev, Vladimir; Filippov, Anatoly; Lin, Ching-Yeh; Coote, Michelle

Description

Spin traps have been used to obtain the first direct experimental determination of the addition (5 × 106 L mol-1 s-1), fragmentation (8 × 10-3 s-1) and self-termination (6.5 × 102 L mol-1 s-1) rate coefficients in RAFT polymerization using the interact

CollectionsANU Research Publications
Date published: 2010
Type: Journal article
URI: http://hdl.handle.net/1885/60700
Source: Polymer Chemistry
DOI: 10.1039/c0py00245c

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