Reversing RAFT Polymerization: Near-Quantitative Monomer Generation Via a Catalyst-Free Depolymerization Approach
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Wang, Hyun Suk; Truong, Nghia P.; Pei, Zhipeng; Coote, Michelle; Anastasaki, Athina
Description
The ability to reverse controlled radical polymerization and regenerate the monomer would be highly beneficial for both fundamental research and applications, yet this has remained very challenging to achieve. Herein, we report a near-quantitative (up to 92%) and catalyst-free depolymerization of various linear, bulky, cross-linked, and functional polymethacrylates made by reversible addition-fragmentation chain-transfer (RAFT) polymerization. Key to our approach is to exploit the high...[Show more]
Collections | ANU Research Publications |
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Date published: | 2022-03-16 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/303321 |
Source: | Journal of the American Chemical Society |
DOI: | 10.1021/jacs.2c00963 |
Access Rights: | Open Access |
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wang-et-al-2022-reversing-raft-polymerization-near-quantitative-monomer-generation-via-a-catalyst-free-depolymerization.pdf | 2.93 MB | Adobe PDF |
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