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Mixed-Metal Cluster Chemistry. 28. Core Enlargement of Tungsten-Iridium Clusters with Alkynyl, Ethyndiyl, and Butadiyndiyl Reagents

Dalton, Gulliver; Viau, Lydie; Waterman, Susan; Humphrey, Mark; Bruce, Michael; Low, Paul J; Roberts, Rachel; Willis, Anthony; Koutsantonis, George; Skelton, Brian; White, Allan

Description

Reaction of [Wlr3(μ-CO)3(CO)8(η- C5Me5)] (1c) with [W(C=CPh)(CO)3(η-C5H5)] afforded the edge-bridged tetrahedral cluster [W2lr 3(μ4-η2-C2Ph)(μ-CO)(CO) 9(η-C5H5)(η-C5Me 5)] (3) and the edge-bridged trigonal-bipyramidal cluster [W 3lr3(μ4-η2-C 2Ph

CollectionsANU Research Publications
Date published: 2005
Type: Journal article
URI: http://hdl.handle.net/1885/29970
Source: Inorganic Chemistry
DOI: 10.1021/ic050040+

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