Reproducible flaws unveil electrostatic aspects of semiconductor electrochemistry
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Vogel, Yan B; Zhang, Long; Darwish, Nadim; Goncales, Vinicius R.; Le Brun, Anton; Gooding, J Justin; Molina, Angela; wallace, Gordon; Coote, Michelle; Gonzalez, Joaquin; Ciampi, Simone
Description
Predicting or manipulating charge-transfer at semiconductor interfaces, from molecular electronics to energy conversion, relies on knowledge generated from a kinetic analysis of the electrode process, as provided by cyclic voltammetry. Scientists and engineers encountering non-ideal shapes and positions in voltammograms are inclined to reject these as flaws. Here we show that non-idealities of redox probes confined at silicon electrodes, namely full width at half maximum <90.6 mV and...[Show more]
Collections | ANU Research Publications |
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Date published: | 2017 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/247764 |
Source: | Nature Communications |
DOI: | 10.1038/s41467-017-02091-1 |
Access Rights: | Open Access |
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