Efficient crystallization-induced emission in fluorenyl-tethered carboranes
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Wang, Zhaojin; Wang, Tianyu; Zhang, Chi; Humphrey, Mark
Description
Fluorenyl-tethered o-carborane derivatives (Fl-Cb) as both mono- and di-aryl Cb assemblies were synthesized from the corresponding alkyne and B10H12(Et2S)2 in ca. 60% yields. Crystallographic studies of di-aryl examples show rigid head-to-tail or tail-to-tail packing, while for the mono-aryl examples, only loose packing was observed. In solution, the Fl-Cb compounds exhibit strong quenching of their emission, while aggregation in a mixed solvent results in an enhanced, but still weak, emission...[Show more]
Collections | ANU Research Publications |
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Date published: | 2017 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/237288 |
Source: | Physical Chemistry Chemical Physics |
DOI: | 10.1039/c7cp02118f |
Access Rights: | Open Access |
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File | Description | Size | Format | Image |
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Efficient crystallization-induced emission_AAM.pdf | 1.57 MB | Adobe PDF |
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