Diene-Transmissive Enantioselective Diels-Alder Reactions and Sequences Involving Substituted Dendralenes
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Sherburn, Michael; George, Josemon
Description
Readily available and stable substituted [3]- dendralenes undergo highly chemo-, regio-, diastereo-, and enantioselective organocatalyzed Diels−Alder reactions with acrolein to form enantiomerically enriched cycloadducts. These monocycloadducts carry semicyclic dienes that undergo a second, substrate-controlled diastereoselective Diels−Alder reaction with a different dienophile to form 2-fold cycloadducts. Overall, annulated, functional group rich, chiral Δ1(9)- octalin building blocks...[Show more]
Collections | ANU Research Publications |
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Date published: | 2019 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/211324 |
Source: | Journal of Organic Chemistry |
DOI: | 10.1021/acs.joc.9b02296 |
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01_Sherburn_Diene-Transmissive_2019.pdf | 1.29 MB | Adobe PDF | Request a copy |
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