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Substituent Effects on Photoinitiation Ability of Monoaminoanthraquinone-Based Photoinitiating Systems for Free Radical Photopolymerization under LEDs

Zhang, Jing; Lalevée, Jacques; Hill, Nicholas S; Kiehl, Jonathan; Zhu, Di; Cox, Nicholas; Langley, Julien; Stenzel, Martina H; Coote, Michelle; Xiao, Pu


Three monoamino-substituted anthraquinone derivatives (AAQs), that is, 1-aminoanthraquinone (AAQ), 1-(methylamino)anthraquinone (MAAQ), and 1-(benzamido)anthraquinone (BAAQ), incorporated with various additives [e.g., triethanolamine (TEAOH) and phenacyl bromide (PhC(═O)CH2 Br)] are investigated for their roles as photoinitiating systems of free radical photopolymerization of (meth)acrylate monomers upon the exposure to UV to green LEDs. The AAQs-based photoinitiating systems,...[Show more]

CollectionsANU Research Publications
Date published: 2020-05-08
Type: Journal article
Source: Macromolecular rapid communications
DOI: 10.1002/marc.202000166
Access Rights: Open Access


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