Effect of Chemical Structure on the Electrochemical Cleavage of Alkoxyamines
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Hammill, Chelsey; Noble, Ben; Norcott, Philip; Ciampi, Simone; Coote, Michelle
Description
A test set of 14 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO)-based alkoxyamines was studied via a combination of cyclic voltammetry and accurate quantum chemistry to assess the effect of substituents on electrochemical cleavage. The experimental oxidation potentials of alkoxyamines falling into the range of 1.1–1.6 V versus Ag/AgCl in acetonitrile, were well reproduced by theory (MAD 0.04 V), with values showing good correlation with the σR Hammett parameters of both the R-group and the...[Show more]
Collections | ANU Research Publications |
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Date published: | 2019-02-13 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/201380 |
Source: | Journal of Physical Chemistry C |
DOI: | 10.1021/acs.jpcc.8b12545 |
Access Rights: | Open Access |
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Redox-paper-CH.pdf | 720.56 kB | Adobe PDF |
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