Long minority carrier lifetime in Au-catalyzed GaAs/AlxGa1−xAs core-shell nanowires

Abstract

GaAs/AlxGa1xAs core-shell nanowires were grown by metal organic chemical vapor deposition with optimized AlxGa1xAs shell and twin-free Au-catalyzed GaAs cores. Time-resolved photoluminescence measurements were carried out on single nanowires at room temperature, revealing minority carrier lifetimes of 1.02 6 0.43 ns, comparable to self-assisted nanowires grown by molecular beam epitaxy. The long minority carrier lifetimes are mainly attributed to improvement of the GaAs/AlxGa1xAs interface quality. The upper limit of surface recombination velocity of the structure is calculated to be 1300 cm/s with the AlxGa1xAs shell grown at 750 C, which is comparable with planar double heterostructures.