Magnetic and electrochemical studies of some encapsulated metal ions
The encapsulation of transition metal ions by hexadentate ligands of the macrobicyclic type involving saturated nitrogen donor atoms is the topic of this thesis. The presence of the metals V, Cr, Mn, Fe, Co, Ni and Cu in the centre of the ligand cage, has enabled the electronic structures of these cage complexes to be probed and elucidated by techniques such as magnetism, NMR, visible and ultraviolet spectroscopy in both the solid and solution states. Magnetic susceptibilities were...[Show more]
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