Martin, Lisandra Lorraine
The encapsulation of transition metal ions by hexadentate
ligands of the macrobicyclic type involving saturated nitrogen donor
atoms is the topic of this thesis. The presence of the metals V, Cr,
Mn, Fe, Co, Ni and Cu in the centre of the ligand cage, has enabled
the electronic structures of these cage complexes to be probed and
elucidated by techniques such as magnetism, NMR, visible and
ultraviolet spectroscopy in both the solid and solution states.
Magnetic susceptibilities were...[Show more]
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