Susceptible Ferroelectric/Antiferroelectric Phase Transition near the Surface of Nb-Doped Lead Zirconate Stannate Titanate from Surface Processing
| dc.contributor.author | Lu, Teng | |
| dc.contributor.author | Studer, Andrew J | |
| dc.contributor.author | Cortie, David | |
| dc.contributor.author | Lau, Kenny | |
| dc.contributor.author | Yu, Dehong | |
| dc.contributor.author | Feng, Yujun | |
| dc.contributor.author | Chen, Hua | |
| dc.contributor.author | Xu, Zhuo | |
| dc.contributor.author | Withers, Ray L | |
| dc.contributor.author | McIntyre, Garry J | |
| dc.contributor.author | Liu, Yun | |
| dc.date.accessioned | 2020-03-12T03:07:34Z | |
| dc.date.available | 2020-03-12T03:07:34Z | |
| dc.date.issued | 2016-06-15 | |
| dc.description.abstract | This work systematically investigated the structure and property of the near-surface and bulk regions of Pb0.99(Nb0.02Zr0.73Sn0.21Ti0.04)O3 ceramics using a combination of X-ray and neutron diffraction, piezoresponse force microscopy, and conventional ferroelectric/piezoelectric characterization. It is found that mechanical force can induce an antiferroelectric/ferroelectric phase transition within micrometers of the surface. Such a phase transition is strongly dependent on the processing scenario, leading to differences from the bulk region. This work provides crucial insights into the sensitivity of this class of AFE materials. Clearly, surface processing conditions must be taken into account for both accurate structural determination and practical applications. | en_AU |
| dc.description.sponsorship | T.L., D.C., Y.L., and R.L.W. thank the Australian Research Council (ARC) for financial support from in the form of a joint ARC Discovery Project. YL also acknowledges the ARC’s support in the form of an ARC Future Fellowship. | en_AU |
| dc.format.mimetype | application/pdf | en_AU |
| dc.identifier.issn | 1944-8244 | en_AU |
| dc.identifier.uri | http://hdl.handle.net/1885/202142 | |
| dc.language.iso | en_AU | en_AU |
| dc.provenance | http://sherpa.ac.uk/romeo/issn/1944-8244/..."author can archive post-print (ie final draft post-refereeing). 12 months embargo" from SHERPA/RoMEO site (as at 12/03/2020). This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS applied materials & interfaces, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://dx.doi.org/10.1021/acsami.6b02868 | en_AU |
| dc.publisher | American Chemical Society | en_AU |
| dc.relation | http://purl.org/au-research/grants/arc/DP160104780 | |
| dc.rights | © 2016 American Chemical Society | en_AU |
| dc.source | ACS applied materials & interfaces | en_AU |
| dc.subject | pfm | en_AU |
| dc.subject | pnzst | en_AU |
| dc.subject | x-ray diffraction | en_AU |
| dc.subject | antiferroelectrics | en_AU |
| dc.subject | ferroelectrics | en_AU |
| dc.subject | neutron diffraction | en_AU |
| dc.subject | surface | en_AU |
| dc.title | Susceptible Ferroelectric/Antiferroelectric Phase Transition near the Surface of Nb-Doped Lead Zirconate Stannate Titanate from Surface Processing | en_AU |
| dc.type | Journal article | en_AU |
| dcterms.accessRights | Open Access | en_AU |
| local.bibliographicCitation.issue | 23 | en_AU |
| local.bibliographicCitation.lastpage | 14317 | en_AU |
| local.bibliographicCitation.startpage | 14313 | en_AU |
| local.contributor.affiliation | Lu, Teng, Research School of Chemistry, The Australian National University | en_AU |
| local.contributor.affiliation | Cortie, D., Research School of Chemistry, The Australian National University | en_AU |
| local.contributor.affiliation | Lau, K., Research School of Chemistry, The Australian National University | en_AU |
| local.contributor.affiliation | Chen, H., Centre for Advanced Microscopy, The Australian National University | en_AU |
| local.contributor.affiliation | Withers, R. L., Research School of Chemistry, The Australian National University | en_AU |
| local.contributor.affiliation | Liu, Y., Research School of Chemistry, The Australian National University | en_AU |
| local.contributor.authoremail | Yun.liu@anu.edu.au | en_AU |
| local.contributor.authoruid | u4036265 | en_AU |
| local.identifier.citationvolume | 8 | en_AU |
| local.identifier.doi | 10.1021/acsami.6b02868 | en_AU |
| local.identifier.essn | 1944-8252 | en_AU |
| local.identifier.uidSubmittedBy | u1005913 | en_AU |
| local.publisher.url | https://pubs.acs.org/ | en_AU |
| local.type.status | Accepted Version | en_AU |