Cyclic enones as substrates in the Morita-Baylis-Hillman reaction: surfactant interactions, scope and scalability with an emphasis on formaldehyde
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Schwartz, Brett; Porzelle, Achim; Jack, Kevin S; Faber, Jonathan M; Gentle, Ian Ross; Williams, Craig
Description
Traditionally, cyclic enones and formalin are reactants notorious for displaying problematic behaviour (i.e., poor solubility and low yields) under Morita-Baylis-Hillman (MBH) reaction conditions. The body of research presented herein focuses on the use of surfactants in water as a solvent medium that offers a resolution to many of the issues associated with the MBH reaction. Reaction scope, scalability and small angle X-ray scattering have been studied to assist with the understanding of the...[Show more]
Collections | ANU Research Publications |
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Date published: | 2009 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/59613 |
Source: | Advanced Synthesis & Catalysis |
DOI: | 10.1002/adsc.200800739 |
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