Skip navigation
Skip navigation

Experimental and Theoretical Studies of the Redox Potentials of Cyclic Nitroxides

Blinco, James P.; Hodgson, Jennifer; Morrow, Benjamin J.; Walker, James R.; Will, Geoffrey D.; Coote, Michelle; Bottle, Steven E

Description

(Chemical Equation Presented) The redox potentials of 25 cyclic nitroxides from four different structural classes (pyrrolidine, piperidine, isoindoline, and azaphenalene) were determined experimentally by cyclic voltammetry in acetonitrile, and also via high-level ab initio molecular orbital calculations. It is shown that the potentials are influenced by the type of ring system, ring substituents and/or groups surrounding the radical moiety. For the pyrrolidine, piperidine, and isoindolines...[Show more]

CollectionsANU Research Publications
Date published: 2008
Type: Journal article
URI: http://hdl.handle.net/1885/53792
Source: Journal of Organic Chemistry
DOI: 10.1021/jo801099w

Download

File Description SizeFormat Image
01_Blinco_Experimental_and_Theoretical_2008.pdf664.14 kBAdobe PDF    Request a copy


Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.

Updated:  12 November 2018/ Responsible Officer:  University Librarian/ Page Contact:  Library Systems & Web Coordinator