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Experimental and Theoretical Studies of the Redox Potentials of Cyclic Nitroxides

Blinco, James P.; Hodgson, Jennifer; Morrow, Benjamin J.; Walker, James R.; Will, Geoffrey D.; Coote, Michelle; Bottle, Steven E


(Chemical Equation Presented) The redox potentials of 25 cyclic nitroxides from four different structural classes (pyrrolidine, piperidine, isoindoline, and azaphenalene) were determined experimentally by cyclic voltammetry in acetonitrile, and also via high-level ab initio molecular orbital calculations. It is shown that the potentials are influenced by the type of ring system, ring substituents and/or groups surrounding the radical moiety. For the pyrrolidine, piperidine, and isoindolines...[Show more]

CollectionsANU Research Publications
Date published: 2008
Type: Journal article
Source: Journal of Organic Chemistry
DOI: 10.1021/jo801099w


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