Paterson, IanDoughty, Victoria A.Florence, GordonGerlach, KaiMcLeod, Malcolm D.Scott, Jeremy P.Trieselmann, Thomas2026-01-012026-01-010097-6156https://hdl.handle.net/1885/733799426The chiral boron enolates 7-14 add to aldehydes with high levels of stereocontrol in a predictable sense. These enolates are designed specifically for the aldol-based construction of the highly oxygenated and stereochemically challenging structures found in polyketide natural products, as illustrated here by their application to the total synthesis of concanamycin F and discodermolide.12en200110.1021/bk-2001-0783.ch0140042850737