Colebatch, AnnieCade, IanHill, AnthonyBhadbhade, Mohan M.2015-12-100276-7333http://hdl.handle.net/1885/62368The reaction of the propargylic salt [Ph3PCH2Cî - CH]PF6 with [Pt(C2H4)(PPh3) 2] affords the η2-allenylphosphonium salt [Pt(η2-CH2î - "Cî - "CHPPh 3)(PPh3)2]PF6 via a metal-mediated propargylic rearrangement. Isomerization of the complex occurs in soKeywords: Alkynyls; Allenyl; Allenyl species; Computational studies; Coordination reactions; Isomerization; Isomers; Platinumη 2 -Allenyl- and η 2 -Alkynylphosphonium Complexes of Platinum201310.1021/om400406s2016-02-24