Organometallic complexes for nonlinear optics Part 21. Syntheses and quadratic hyperpolarizabilities of alkynyl complexes containing optically active 1,2-bis(methylphenylphosphino)benzene ligands

McDonagh, AndrewCifuentes, MarieHoubrechts, StephanMaes, JoachimPersoons, Andre PierreSamoc, MarekLuther-Davies, BarryHumphrey, Mark2015-12-130022-328Xhttp://hdl.handle.net/1885/91194The preparation of the chloro complex trans-[FeCl2{(R,R)-diph}2] (1) and the alkynyl complexes trans-[M(4-C≡CC6H4R)Cl{(R,R)-diph}2] [M = Fe, R = NO2 (2); M = Ru, R = H (4), NO2 (5), (E)-CH=CH-4-C6H4NO2 (6); M = Os, R = NO2 (7)], incorporating the opticaKeywords: Alkynyl; Chiral diphosphine; Cyclic voltammetry; Iron; Nonlinear optics; Osmium; Quadratic hyperpolarizabilities; RutheniumOrganometallic complexes for nonlinear optics Part 21. Syntheses and quadratic hyperpolarizabilities of alkynyl complexes containing optically active 1,2-bis(methylphenylphosphino)benzene ligands200010.1016/S0022-328X(00)00420-42015-12-12