Organometallic Tantalum Tris(methimazolyl)borato Complexes: [Ta( η 2 -RC≡CR)Cl 2 {HB(mt) 3 }] (R = Ph, Et; mt = methimazolyl)

Hill, AnthonySmith, Matthew2015-12-080276-7333http://hdl.handle.net/1885/31684The reactions of Na[HB(mt)3] (mt = methimazolyl) with [Ta(η2-RC≡CR)Cl3(dme)] (R = Ph, Et) provide the structurally characterized complexes [Ta(η2-RC≡CR)Cl 2{HB(mt)3}], the first examples of organometallic tris( methimazolyl )borato derivatives of grKeywords: Chirality; Derivatives; Metal complexes; Molecular orientation; Reaction kinetics; Tantalum compounds; Alkyne orientation; Borato derivatives; Organometallic derivatives; Structurally characterized complexes; OrganometallicsOrganometallic Tantalum Tris(methimazolyl)borato Complexes: [Ta( η 2 -RC≡CR)Cl 2 {HB(mt) 3 }] (R = Ph, Et; mt = methimazolyl)200710.1021/om700615w2015-12-08