Homoleptic cerium(III) and cerium(IV) nitroxide complexes: Significant stabilization of the 4+ oxidation state

Bogart, Justin A.Lewis, Andrea J.Medling, ScottPiro, Nicholas A.Carroll, Patrick J.Booth, Corwin H.Schelter, Eric J.2015-12-100020-1669http://hdl.handle.net/1885/64912Electrochemical experiments performed on the complex CeIV[2- (tBuNO)py]4, where [2-(tBuNO)py]- = N-tert-butyl-N-2-pyridylnitroxide, indicate a 2.51 V stabilization of the 4+ oxidation state of Ce compared to [nBu4N] 2[Ce(NO3)6] in acetonitrile and a 2.95Homoleptic cerium(III) and cerium(IV) nitroxide complexes: Significant stabilization of the 4+ oxidation state201310.1021/ic401974t2015-12-10